Atomic Number: |
96 |
Atomic Symbol: |
Cm |
Atomic Weight: |
247 |
Electron Configuration: |
[Rn]7s25f76d1 |
History
(Pierre and Marie Curie) Although curium follows americium in the periodic system, it
was actually known before americium and was the third transuranium element to be
discovered. It was identified by Seaborg, James, and Ghiorso in 1944 at the wartime
Metallurgical Laboratory in Chicago as a result of helium-ion bombardment of 239Pu in the
Berkeley, California, 60-inch cyclotron. Visible amounts (30Mg) of 242Cm, in the form of
the hydroxide, were first isolated by Werner and Perlman of the University of California
in 1947. In 1950, Crane, Wallmann, and Cunningham found that the magnetic susceptibility
of microgram samples of CmF3 was of the same magnitude as that of GdF3. This provided
direct experimental evidence for assigning an electronic configuration to Cm+3. In 1951, the same workers prepared
curium in its elemental form for the first time. Fourteen isotopes of curium are now
known. The most stable, 247Cm, with a half-life of 16 million years, is so short compared
to the earth's age that any primordial curium must have disappeared long ago from the
natural scene. Minute amounts of curium probably exist in natural deposits of uranium, as
a result of a sequence of neutron captures and beta decays sustained by the very low flux
of neutrons naturally present in uranium ores. The presence of natural curium, however,
has never been detected. 242Cm and 244Cm are available in multigram quantities. 248Cm has
been produced only in milligram amounts. Curium is similar in some regards to gadolinium,
its rare earth homolog, but it has a more complex crystal structure. Curium is silver in
color, is chemically reactive, and is more electropositive than aluminum. Most compounds
of trivalent curium are faintly yellow in color. 242 Cm generates about three watts of
thermal energy per gram. This compares to one-half watt per gram of 238Pu. This suggests
use for curium as a power source. 244Cm is now offered for sale at $100/mg. Curium
absorbed into the body accumulates in the bones, and is therefore very toxic as its
radiation destroys the red-cell forming mechanism. The maximum permissible total body
burden of 244Cm (soluble) in a human being is 0.3 microcurie.
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