For lamp filaments.
Atomic Number: |
74 |
Atomic Symbol: |
W |
Atomic Weight: |
183.5 |
Electron Configuration: |
[Xe]6s24f145d4 |
History
(Swedish, tung sten, heavy stone) In 1779 Peter Woulfe examined the mineral now known
as wolframite and concluded it must contain a new substance. Scheele, in 1781, found that
a new acid could be made from tungsten (a name first applied about 1758 to a mineral now
known as scheelite). Scheele and Berman suggested the possibility of obtaining a new metal
by reducing this acid. The de Elhuyar brothers found acid in wolframite in 1783 that was
identical to the acid of tungsten (tungstic acid) of Scheele, and in that year they
succeeded in obtaining the element by reduction of this acid with charcoal. Tungsten
occurs in wolframite, scheelite, huebnertie, and ferberite. Important deposits of tungsten
occur in California, Colorado, South Korea, Bolivia, Russia, and Portugal. China is
reported to have about 75% of the world's tungsten resources. Natural tungsten contains
five stable isotopes. Twenty one other unstable isotopes are recognized. The metal is
obtained commercially be recucing tungsten oxide with hydrogen or carbon. Pure tungsten is
a stelel-gray to tin-white metal. Very pure tungsten can be cut with a hacksaw, and can be
forged, spun, drawn, and extruded. The impure metal is brittle and can be worked only with
difficulty. Tungsten has the highest melting point of all metals, and at temperatures over
1650oC has the highest
tensile strength. The metal oxidizes in air and must be protected at elevated
temperatures. It has excellent corrosion resistance and is attacked only slightly by most
mineral acids. The thermal expansion is about the same as borosilicate glass, which makes
the metal useful for glass-to-metal seals. tungsten and its alloys are used extensively
for filaments for electric lamps, electron and television tubes, and for metal evaporation
work; for electrical contact points for automobile distributors; X-ray targets; windings
and heating elements for electrical furnaces; and for numerous spacecraft and
high-temperature applications. High-speed tool steels, Hastelloy(R), Stellite(R), and many
other alloys contain tungsten. Tungsten carbide is of great importance to the
metal-working, mining, and petroleum industries. Calcium and magnesium tungstates are
widely used in fluorescent lighting; other salts of tungsten are used in the chemical and
tanning industries. Tungsten disulfide is a dry, high-temperature lubricant, stable to
500C. Tungsten bronzes and other tungsten compounds are used in paints. Tungsten powder
(99.9%) costs about $50/lb.
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